Classification of Elements and Periodicity in Properties MCQ Questions & Answers in Inorganic Chemistry | Chemistry
Learn Classification of Elements and Periodicity in Properties MCQ questions & answers in Inorganic Chemistry are available for students perparing for IIT-JEE, NEET, Engineering and Medical Enternace exam.
121.
$$N{a^ + },M{g^{2 + }},A{l^{3 + }}$$ and $$S{i^{4 + }}$$ are isoelectronic. The order of their ionic size is
Among the isoelectronic species, the cation having more positive charge would be the smaller in size.
122.
Consider the following four elements, which are represented according to long form of periodic table.
Here $$W, Y$$ and $$Z$$ are left, up and right elements with respect to the element $$'X'$$ and $$'X'$$ belongs to 16th group and 3rd period. Then according to given information the incorrect statement regarding given elements is:
A
Maximum electronegativity : $$Y$$
B
Maximum catenation property : $$X$$
C
Maximum electron affinity : $$Z$$
D
$$Y$$ exhibits variable covalency
Answer :
$$Y$$ exhibits variable covalency
$$\eqalign{
& W:{\text{Phosphorus}}\,\,\,\,\,\,\,\,\,\,\,Y:{\text{Oxygen}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,\,X:\,\,{\text{Sulphur}}\,\,\,\,\,\,\,\,\,\,\,\,\,\,Z:{\text{Chlorine}} \cr
& {\text{Electronegativity}}\,\,\,\,\,\,\,O > Cl > S > P\,\,\,\,\,\,\,{\text{Catenation :}}\,\,\,\,\,\,\,\,\,\,\,\,S > P > O > Cl \cr
& {\text{Electron Affinity :}}\,\,\,\,\,Cl > O > S > P\,\,\,\,\,\,\,{\text{Oxygen exhibits covalency of two only}} \cr} $$
123.
Which of the following electronic configurations is of transition elements?
A
$$1{s^2}2{s^2}2{p^6}3{s^2}3{p^6}4{s^2}$$
B
$$1{s^2}2{s^2}2{p^6}3{s^2}3{p^6}3{d^{10}}4{s^2}4{p^1}$$
C
$$1{s^2}2{s^2}2{p^6}3{s^2}3{p^6}3{d^{10}}4{s^2}4{p^6}$$
Since last electron enter in $$d$$ - orbital, it is a transition element.
124.
Electronic configurations of four elements $$A, B, C$$ and $$D$$ are given below :
$$\eqalign{
& \left( A \right)1{s^2}2{s^2}2{p^6} \cr
& \left( B \right)1{s^2}2{s^2}2{p^4} \cr
& \left( C \right)1{s^2}2{s^2}2{p^6}3{s^1} \cr
& \left( D \right)1{s^2}2{s^2}2{p^5} \cr} $$
Which of the following is the correct order of increasing tendency to gain electron?
125.
Few values are given in the table in the direction from left to right and top to bottom. Predict the property which could be depicted in the table.
A
Atomic number
B
Ionisation enthalpy
C
Atomic radius
D
Electron gain enthalpy
Answer :
Atomic radius
Atomic radius decreases in a period from left to right and increases in a group from top to bottom.
126.
Which of the following order is wrong ?
A
$$N{H_3} < P{H_3} < As{H_3} - {\text{Acidic}}$$
B
$$Li < Be < B < C - I{E_1}$$
C
$$A{l_2}{O_3} < MgO < N{a_2}O < {K_2}O - {\text{Basic}}$$
The right sequence of $$I.{E_1}$$ of $$Li < B < Be < C.$$
127.
Which of the following is arranged in order of increasing metallic character?
A
$$P < Si < Na < Be < Mg$$
B
$$Be < Mg < P < Na < Si$$
C
$$Si < Be > Mg < Na < P$$
D
$$P < Si < Be < Mg < Na$$
Answer :
$$P < Si < Be < Mg < Na$$
Metallic character increases down a group and decreases along a period as we move from left to right.
Hence, the order of increasing metallic character is : $$P < Si < Be < Mg < Na$$
128.
The electronic configuration of an element is . The atomic number and the group number of the element $$'X'$$ which is just below the above element in the periodic table are respectively
A
23 and 5
B
23 and 15
C
33 and 15
D
33 and 5
Answer :
33 and 15
Atomic number of the given element $$=15;$$
atomic number of element $$'X'$$ will be $$18+15=33;$$
group no. of $$'X'=10+5$$ ( valence electrons ) $$=15,$$ period = 4th
129.
The set of three elements having successive atomic numbers and having the ionization energies of $$2372, 520$$ and $$890\,kJ$$ per $$mol$$ is
A
$$H,He,Li$$
B
$$He,Li,Be$$
C
$$Li,Be,B$$
D
$$B,C,N$$
Answer :
$$He,Li,Be$$
He $$(Z = 2)$$ is a noble gas and has highest $$I.E.$$ The $$I.E.$$ of $$Be (Z = 4)$$ is more than that of
$$Li (Z = 3)$$
130.
Which one of the following statements is incorrect in relation to ionisation enthalpy ?
A
Ionisation enthalpy increases for each successive electron.
B
The greatest increase in ionisation enthalpy is experienced on removal of electron from core noble gas configuration.
C
End of valence electrons is marked by a big jump in ionisation enthalpy.
D
Removal of electron from orbitals bearing lower $$n$$ value is easier than from orbital having higher $$n$$ value.
Answer :
Removal of electron from orbitals bearing lower $$n$$ value is easier than from orbital having higher $$n$$ value.
As the value of $$n$$ increases, the nuclear attraction over the outermost shell decreases, therefore removal of an electron will be easier.