General Organic Chemistry MCQ Questions & Answers in Organic Chemistry | Chemistry
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161.
Which of the following will not give a white ppt. when $$AgN{O_3}$$ is added to its solution?
A
$$CC{l_4}$$
B
$$NaCl$$
C
$$MgC{l_2}$$
D
$$KCl$$
Answer :
$$CC{l_4}$$
$$CC{l_4}$$ being covalent will not furnish chloride ions which on reaction with $$A{g^ + }$$ form a white ppt.
162.
Which of the following molecules is expected to rotate the plane of plane - polarised light ?
A
B
C
D
Answer :
NOTE : The organic compounds which have chiral carbon atom (a carbon atom attached to four different group or atoms and do not have plane of symmetry rotate plane polarised light.
163.
Which of the following is the $$IUPAC$$ name of the compound
The compound is a derivative of benzaldehyde. Start numbering $$C$$ - atoms of benzene nucleus from $$C$$ - atom bearing – $$CHO$$ group.
164.
In which of the following compounds electrophilic aromatic substitution takes place in phenyl ring present in left hand side $$(LHS)?$$
A
(a)
B
(b)
C
(c)
D
(d)
Answer :
(d)
$${E^ + }$$ attacks on ring which has more $${e^ - }$$ density.
165.
Which one of the following is a free radical substitution reaction ?
A
B
C
D
Answer :
At higher temperature the reaction of toluene with chlorine is an example of free radical substitution.
166.
The $$(R)$$ - and $$(S)$$ - enantiomers of an optically active compound differ in
A
their solubility in a chiral solvent
B
their reactivity with a chiral reagent
C
their optical rotation of plane polarised light
D
their melting points
Answer :
their optical rotation of plane polarised light
$$R$$ and $$S$$ forms of an optically active compound differ in their behaviour towards plane polarised light. The species which rotate the plane polarised
light towards right is called $$R$$ - form ( $$rectus$$ form ) or $$d$$ - form ( $$dextro$$ - form ) and the species which rotate the plane polarised light towards left is known as $$S$$ - form ( $$sinister$$ - form ) or $$l$$ - form ( $$laevo$$ - form ).
167.
In Lassaigne's test for $$N, S$$ and halogens, the organic compound is
A
fused with sodium
B
dissolved with sodamide
C
extracted with sodamide
D
fused with calcium
Answer :
fused with sodium
No explanation is given for this question. Let's discuss the answer together.
168.
The correct IUPAC name of the following compound is :