General Organic Chemistry MCQ Questions & Answers in Organic Chemistry | Chemistry
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201.
Which of the following possesses a $$sp$$ - carbon in its structure?
A
$$C{H_2} = CCl - CH = C{H_2}$$
B
$$CC{l_2} = CC{l_2}$$
C
$$C{H_2} = C = C{H_2}$$
D
$$C{H_2} = CH - CH = C{H_2}$$
Answer :
$$C{H_2} = C = C{H_2}$$
In structure $$C{H_2} = C = C{H_2},$$ the middle carbon is attached with two $$\pi $$ -bonds, so it have $$sp$$ hybridisation.
$$\mathop {C{H_2}}\limits_{s{p^2}} = \mathop C\limits_{sp} = \mathop {C{H_2}}\limits_{s{p^2}} $$
Also, called allenes.
202.
Which one of the following is most reactive towards electrophilic reagent?
A
B
C
D
Answer :
Due to $$ + M$$ - effect of $$ - OH$$ group and hyperconjugation of $$ - C{H_3}$$ group, the benzene of $$o$$ - cresol is highly reactive towards electrophilic substitution.
203.
Which of the following is optically active ?
A
B
C
D
Answer :
204.
The IUPAC name of is
A
1-chloro-1-oxo-2, 3-dimethylpentane
B
2-ethyl-3-methylbutanoyl chloride
C
2, 3-dimethylpentanoyl chloride
D
3, 4-dimethylpentanoyl chloride
Answer :
2, 3-dimethylpentanoyl chloride
205.
The IUPAC name of $${C_6}{H_5}COCl$$ is
A
Benzene chloro ketone
B
Benzoyl chloride
C
Chloro phenyl ketone
D
Benzene carbonyl chloride
Answer :
Benzoyl chloride
Carboxylic acids are named as oyl chlorides.
206.
Which of the following is the correct IUPAC name?
A
3-Ethyl-4, 4-dimethylheptane
B
4, 4-Dimethyl-3-ethylheptane
C
5-Ethyl-4, 4-dimethylheptane
D
4, 4-Bis(methyl) -3-ethylheptane
Answer :
3-Ethyl-4, 4-dimethylheptane
No explanation is given for this question. Let's discuss the answer together.
207.
Those substances can be separated by steam distillation are
A
steam volatile and insoluble in water
B
steam volatile and soluble in water
C
steam volatile and sparingly soluble in water
D
in liquid form in steam and solid form in water
Answer :
steam volatile and insoluble in water
No explanation is given for this question. Let's discuss the answer together.
208.
Electronegativity of carbon atoms depends upon their state of hybridisation. In which of the following compounds, the carbon marked with asterisk is most electronegative?
The greater the $$s$$ character of the hybrid orbitals, the greater is the electronegativity. Thus, a carbon atom having an $$sp$$ hybrid orbital with $$50\% \,s$$ character is more electronegative than those possessing $$s{p^2}$$ or $$s{p^3}$$ hybridised orbitals .
The asterisk marked carbon in $$C{H_3} - C{H_2} - C \equiv \mathop C\limits^ * H$$ is $$sp$$ hybridised hence, it is most electronegative.
209.
Dipole moment of which ketone is maximum ?
A
B
C
D
Answer :
so molecule has high dipole moment.
210.
The compound 1, 2-butadiene has
A
only $$sp$$ hybridized carbon atoms
B
only $$s{p^2}$$ hybridized carbon atoms
C
both $$sp$$ and $$s{p^2}$$ hybridized carbon atoms
D
$$sp$$ , $$s{p^2}$$ and $$s{p^3}$$ hybridized carbon atoms
Answer :
$$sp$$ , $$s{p^2}$$ and $$s{p^3}$$ hybridized carbon atoms