Atomic Structure MCQ Questions & Answers in Physical Chemistry | Chemistry

Learn Atomic Structure MCQ questions & answers in Physical Chemistry are available for students perparing for IIT-JEE, NEET, Engineering and Medical Enternace exam.

61. The energy of electron in first energy level is $$ - 21.79 \times {10^{ - 12}}erg$$     per atom. The energy of electron in second energy level is :

A \[-54.47\times {{10}^{-12}}\,erg\,\,ato{{m}^{-1}}\]
B \[-5.447\times {{10}^{-12}}erg\,\,ato{{m}^{-1}}\]
C \[-0.5447\times {{10}^{-12}}erg\,\,ato{{m}^{-1}}\]
D \[-0.05447\times {{10}^{-12}}erg\,\,ato{{m}^{-1}}\]
Answer :   \[-5.447\times {{10}^{-12}}erg\,\,ato{{m}^{-1}}\]

62. Arrange the electromagnetic radiations $$a, b, c, d$$   and $$e$$ in increasing order of energy. Frequencies of $$a, b$$  and $$c$$ are $${10^{15}},{10^{14}}$$   and $${10^{17}}$$  respectively whereas wavelength of $$(d)$$ and $$(e)$$ are $$350\,nm$$   and $$100\,nm$$   respectively ?

A $$a,b,c,d,e$$
B $$a,b,d,e,c$$
C $$a,d,b,e,c$$
D $$b,a,d,e,c$$
Answer :   $$b,a,d,e,c$$

63. Among the following groupings which represents the collection of isoelectronic species?

A $$N{O^ + },C_2^{2 - },O_2^ - ,CO$$
B $${N_2},C_2^{2 - },CO,NO$$
C $$CO,N{O^ + },C{N^ - },C_2^{2 - }$$
D $$NO,C{N^ - },{N_2},O_2^ - $$
Answer :   $$CO,N{O^ + },C{N^ - },C_2^{2 - }$$

64. Which of the following observations was not correct during Rutherford's scattering experiment ?

A Most of the $$\alpha $$ - particles passed through the gold foil undeflected.
B A small fraction of the $$\alpha $$ - particles was deflected by small angles.
C A large number of the $$\alpha $$ - particles were bounced back.
D A very few $$\alpha $$ - particles $$\left( { \sim 1\,\,{\text{in}}\,\,20,000} \right)$$    were bounced back.
Answer :   A large number of the $$\alpha $$ - particles were bounced back.

65. How many electrons can fit in the orbital for which $$n = 3\,{\text{and}}\,I = 1\,?$$

A 2
B 6
C 10
D 14
Answer :   2

66. Which one is not in agreement with Bohr's model of the atom ?

A Line spectra of hydrogen atom
B Pauli's exclusion principle
C Planck's theory
D Heisenberg's uncertainty principle
Answer :   Heisenberg's uncertainty principle

67. Electromagnetic radiation with maximum wavelength is :

A ultraviolet
B radiowave
C $$X-$$ray
D infrared
Answer :   radiowave

68. Consider the following sets of quantum numbers.
$$n$$ $$l$$ $$m$$ $$s$$
(i) 3 0 0 $$ + \frac{1}{2}$$
(ii) 2 2 1 $$ + \frac{1}{2}$$
(iii) 4 3 −2 $$ - \frac{1}{2}$$
(iv) 1 0 −1 $$ - \frac{1}{2}$$
(v) 3 2 3 $$ + \frac{1}{2}$$

Which of the following sets of quantum number is not possible?

A (ii), (iii) and (iv)
B (i), (ii), (iii) and (iv)
C (ii), (iv) and (v)
D (i) and (iii)
Answer :   (i) and (iii)

69. The uncertainty in momentum of an electron is $$1 \times {10^{ - 5}}kg/ms.$$   The uncertainty in its position will be
$$\left( {{\text{Given,}}\,h = 6.62 \times {{10}^{ - 34}}kg\,\,{m^2}/s} \right)$$

A $$1.05 \times {10^{ - 28}}m$$
B $$1.05 \times {10^{ - 26}}m$$
C $$5.27 \times {10^{ - 30}}m$$
D $$5.25 \times {10^{ - 28}}m$$
Answer :   $$5.27 \times {10^{ - 30}}m$$

70. Which of the following sets of quantum numbers is correct for an electron in $$4f$$ orbital ?

A $$n = 4,\,l = 3,\,m = + 1,\,s = + \frac{1}{2}$$
B $$n = 4,\,l = 4,\,m = - 4,\,s = - \frac{1}{2}$$
C $$n = 4,\,l = 3,\,m = + 4,\,s = + \frac{1}{2}$$
D $$n = 3,\,l = 2,\,m = - 2,\,s = + \frac{1}{2}$$
Answer :   $$n = 4,\,l = 3,\,m = + 1,\,s = + \frac{1}{2}$$