Learn Surface Chemistry MCQ questions & answers in Physical Chemistry are available for students perparing for IIT-JEE, NEET, Engineering and Medical Enternace exam.
121.
For a linear plot of $$\log \,\left( {x/m} \right)$$ versus $$\log \,p$$ in a Freundlich adsorption isotherm, which of the following statements is correct? ( $$k$$ and $$n$$ are constants )
A
Only $$\frac{1}{n}$$ appears as the slope.
B
log $$\left( {\frac{1}{n}} \right)$$ appears as the intercept.
C
Both $$k$$ and $$\frac{1}{n}$$ appear in the slope term.
D
$$\frac{1}{n}$$ appears as the intercept.
Answer :
Only $$\frac{1}{n}$$ appears as the slope.
According to Freundlich adsorption isotherm
$$\log \frac{x}{m} = \log K + \frac{1}{n}\,\,\log \,P$$
Thus if a graph is plotted between $$\log \left( {\frac{x}{m}} \right)$$ and $$\log \,p$$ , a straight line will be obtained
The slope of the line is equal to $$\frac{1}{n}$$ and the intercept on $$\log \frac{x}{m}$$ axis will correspond to $$\log \,K.$$
122.
During dialysis
A
only solvent molecules can diffuse
B
solvent molecules, ions and colloidal particles can diffuse
C
all kinds of particles can diffuse through the semipermeable membrane
D
solvent molecules and ions can diffuse
Answer :
solvent molecules and ions can diffuse
The principle of dialysis is based upon the fact that colloidal particles cannot pass through a parchment or cellophane membrane while the ions of the electrolyte can pass through it.
123.
The method usually employed for the precipitation of a colloidal solution is
A
dialysis
B
addition of electrolytes
C
diffusion through animal membrane
D
condensation
Answer :
addition of electrolytes
On addition of electrolyte charge of colloidal particles will neutralise and hence, coagulation or precipitation of colloidal solution will occur.
124.
The cause of Brownian movement is
A
Heat changes in liquid state
B
Convectional currents
C
The impact of molecules of the dispersion medium on the colloidal particles.
D
Attractive forces between the colloidal particles and molecules of dispersion medium.
Answer :
The impact of molecules of the dispersion medium on the colloidal particles.
It is due to impact of molecules of dispersion medium on the colloidal particles.
125.
Which of the following is not correctly matched ?
A
Gelatin - Lyophilic colloid
B
Gold sol - Lyophilic colloid
C
Arsenious sulphide - Lyophobic colloid
D
Ferric hydroxide - Lyophobic colloid
Answer :
Gold sol - Lyophilic colloid
Gold sol is a lyophobic colloid
126.
Given below are a few electrolytes, indicate which one among them will bring about the coagulation of a gold sol quickest and in the least of concentration?
A
$$NaCl$$
B
$$MgS{O_4}$$
C
$$A{l_2}{\left( {S{O_4}} \right)_3}$$
D
$${K_4}\left[ {Fe{{\left( {CN} \right)}_6}} \right]$$
Answer :
$$A{l_2}{\left( {S{O_4}} \right)_3}$$
Gold sol. have negative charge. So $$A{l_2}{\left( {S{O_4}} \right)_3}$$ is most effective for coagulation.
127.
The protecting power of lyophilic colloidal sol is expressed in terms of
A
coagulation value
B
gold number
C
critical micelle concentration
D
oxidation number
Answer :
gold number
Lyophobic sols are unstable, so they are stabilised by adding some lyophilic colloids which protect them from precipitation. Thus, lyophilic colloids are called protecting colloids. Their protecting power is expressed in terms of gold number. In other words, gold number can be defined as the minimum amount of lyophilic colloid in milligrams, which prevent the flocculation of $$10$$ $$mL$$ gold sol by the addition of $$1$$ $$mL$$ of $$10\% \,NaCl$$ solution.
NOTE
Lesser the gold number, higher is the protecting power.
128.
The correct statement for both the processes of physisorption and chemisorption is
A
both are endothermic
B
chemisorption is endothermic but physisorption is exothermic
C
both are exothermic
D
physisorption is endothermic but chemisorption is exothermic.
Answer :
both are exothermic
Both are exothermic.
129.
Cloud or fog is a colloidal system in which the dispersed phase and the dispersion medium are
A
Gas, Liquid
B
Liquid, gas
C
Liquid, liquid
D
Solid, Liquid
Answer :
Liquid, gas
Cloud and fog are colloidal system having dispersed phase liquid and dispersion medium gas
130.
The volume of gases $$N{H_3},C{O_2}$$ and $${H_2}$$ adsorbed
by one gram of charcoal at $$300\,K$$ are in order of :
A
$${H_2} > C{O_2} > N{H_3}$$
B
$$N{H_3} > {H_2} > C{O_2}$$
C
$$N{H_3} > C{O_2} > {H_2}$$
D
$$C{O_2} > N{H_3} > {H_2}$$
Answer :
$$N{H_3} > C{O_2} > {H_2}$$
Van der Waal force $$ \uparrow $$ adsorption $$ \uparrow $$