Polymers MCQ Questions & Answers in Organic Chemistry | Chemistry
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121.
Which one of the following pairs is not correctly matched?
A
Terylene-condensation polymer of terephthalic acid and ethylene glycol
B
Teflon-thermally stable cross-linked polymer of phenol and formaldehyde
C
Perspex-homopolymer of methylmethacrylate
D
Synthetic rubber-a copolymer of butadiene and styrene
Answer :
Teflon-thermally stable cross-linked polymer of phenol and formaldehyde
Teflon is linear addition polymer of tetrafluoroethene.
122.
Heating rubber with sulphur is known as
A
galvanisation
B
bessemerisation
C
vulcanisation
D
sulphonation
Answer :
vulcanisation
No explanation is given for this question. Let's discuss the answer together.
123.
Which of the following structures represents neoprene polymer?
A
B
C
D
Answer :
Neoprene (synthetic rubber) is a polymer of chloroprene, i.e. 2-chloro-1, 3-butadiene.
124.
Structures of some common polymers are given. Which one is not correctly presented?
A
B
C
D
Answer :
Neoprene is a polymer of chloroprene (2-chloro -1,3-butadiene) and also called homopolymer (addition polymer).
125.
Which one of the following structures represents nylon 6, 6 polymer?
A
B
C
D
Answer :
Nylon-6, 6 polymer is formed as
Thus, option (D) is correct.
126.
Natural rubber has
A
All $$trans$$ - configuration
B
Alternate $$cis$$ - and $$trans$$ - configuration
C
Random $$cis$$ - and $$trans$$ - configuration
D
All $$cis$$ - configuration
Answer :
All $$cis$$ - configuration
The repeating unit in natural rubber has the $$cis$$ - configurations with chain extensions on the same side of the ethylene double bond, which is
essential for elasticity. If the configuration is trans, the polymer is either a hard plastic or a substance like $$gutta-percha.$$
Natural rubber
All $$cis$$ - configuration
127.
Among the following, the wrong statement is
A
$$PMMA$$ is plexiglass
B
$$SBR$$ is natural rubber
C
$$PTFE$$ is teflon
D
$$LDPE$$ is low density polythene
Answer :
$$SBR$$ is natural rubber
$$SBR$$ is styrene-butadiene rubber, is a synthetic rubber.
128.
Biodegradable polymer which can be produced from glycine and aminocapric acid is
A
nylon 2-nylon 6
B
$$PHBV$$
C
buna - $$N$$
D
nylon - 6, 6
Answer :
nylon 2-nylon 6
Nylon-2-nylon-6
It is an alternating polyamide of glycine ( containing two carbon atoms ) and amino caproic acid or 6-aminohexanoic acid ( containing six carbon atoms ).
It is a biodegradable step-growth copolymer.
129.
Polymer used in bullet proof glass is
A
lexan
B
$$PMMA$$
C
nomex
D
kevlar
Answer :
$$PMMA$$
$$PMMA$$ and polycarbonate are used in bullet proof glass
130.
The correct functional group $$X$$ and the reagent / reaction conditions $$Y$$ in the following scheme are
$$\eqalign{
& \left( {\text{i}} \right)X = COOC{H_3},Y = {H_2}/Ni/{\text{heat}} \cr
& \left( {{\text{ii}}} \right)X = CON{H_2},Y = {H_2}/Ni/{\text{heat}} \cr
& \left( {{\text{iii}}} \right)X = CON{H_2},Y = B{r_2}/NaOH \cr
& \left( {{\text{iv}}} \right)X = CN,Y = {H_2}/Ni/{\text{heat}} \cr} $$
A
(i) and (ii)
B
(i), (ii) and (iii)
C
(i) and (iii)
D
All of these
Answer :
All of these
Condensation polymers are formed by condensation of diols or diamine with dicarboxylic acids.
Therefore,
$$X$$ may be; \[\overset{\begin{smallmatrix}
O \\
\parallel
\end{smallmatrix}}{\mathop{-C-}}\,OR\,\,\text{or}\,\,\overset{\begin{smallmatrix}
O \\
\parallel
\end{smallmatrix}}{\mathop{-C-}}\,N{{H}_{2}}\,\,\text{or}\,\,-C\equiv N\]
\[\begin{align}
& \overset{\begin{smallmatrix}
O \\
\parallel
\end{smallmatrix}}{\mathop{-C-}}\,OR\xrightarrow[\Delta ]{{{H}_{2}}/Ni}-C{{H}_{2}}OH \\
& \overset{\begin{smallmatrix}
O \\
\parallel
\end{smallmatrix}}{\mathop{-C-}}\,N{{H}_{2}}\xrightarrow{B{{r}_{2}}/NaOH}-N{{H}_{2}} \\
& \overset{\begin{smallmatrix}
O \\
\parallel
\end{smallmatrix}}{\mathop{-C-}}\,N{{H}_{2}}\xrightarrow[\Delta ]{{{H}_{2}}/Ni}-C{{H}_{2}}-N{{H}_{2}} \\
& -C\equiv N\xrightarrow[\Delta ]{{{H}_{2}}/Ni}-C{{H}_{2}}-N{{H}_{2}} \\
\end{align}\]