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191.
Mixing of positively charged colloidal solution with negatively charged colloidal solution brings _________. The decreasing order of coagulating power of $$N{a^ + },B{a^{2 + }}$$ and $$A{l^{3 + }}$$ for negatively charged colloidal solution is __________.
According to Hardy-Schulze rule, the coagulating power of an ion depends upon its valency. Higher the valency of ion, greater is its coagulating power.
192.
For the graph below, select correct order of temperature?
A
$${T_1} > {T_2} > {T_3}$$
B
$${T_2} > {T_3} > {T_1}$$
C
$${T_3} > {T_2} > {T_1}$$
D
$${T_1} = {T_2} = {T_3}$$
Answer :
$${T_3} > {T_2} > {T_1}$$
Temp $$ \uparrow $$ Extent of adsorption $$ \downarrow $$
193.
Which of the following statements is not correct about physisorption?
A
It is a reversible process.
B
It requires less heat of adsorption.
C
It requires activation energy.
D
It takes place at low temperature.
Answer :
It requires activation energy.
Physisorption does not require activation energy since it takes place at low temperature.
194.
The heat evolved in chemisorption lies in the range ( in $$kJ/mol$$ ) of :
195.
Which of the following forms cationic micelles above certain concentration?
A
Sodium ethyl sulphate
B
Sodium acetate
C
Urea
D
Cetyl trimethyl ammonium bromide
Answer :
Cetyl trimethyl ammonium bromide
Cetyltrimethylammonium bromide forms cationic micelles above a certain concentration. In the molecule of detergents and soap, the negative ions aggregate to form a micelle of colloidal size. In polar medium ( like water ), the negative ion has a long hydrocarbon chain and a polar group $$\left( { - CO{O^ - }} \right)$$ at one end and on other end, it has $${N^ + }$$ $$ion,$$ thus cationic micelle is formed.
196.
Which one of the sols acts as protective colloid ?
A
$$A{s_2}{S_3}$$
B
$${\text{Gelatin}}$$
C
$$Au$$
D
$$Fe{\left( {OH} \right)_3}$$
Answer :
$${\text{Gelatin}}$$
Gelatin act as protective colloids.
197.
Butter is a colloid formed when
A
fat is dispersed in water
B
fat globules are dispersed in water
C
water is dispersed in fat
D
None of the these
Answer :
water is dispersed in fat
Butter ( liquid - solid ) water dispersed in fat
198.
Lyophilic sols are more stable than lyophobic sols because :
A
the colloidal particles have positive charge
B
the colloidal particles have negative charge
C
the colloidal particles are solvated
D
there is strong electrostatic repulsion between the colloidal particles
Answer :
the colloidal particles are solvated
$$D.P.$$ particles have great affinity towards $$D.M.$$ in lyophilic colloids.
199.
The oxide of nitrogen which acts as a catalyst in lead chamber process is
If colloidal sol of $$AgI$$ is prepared by adding $$KI$$ solution to $$AgN{O_3}$$ till $$KI$$ is in slight excess, iodide ion $$\left( {{I^ - }} \right)$$ will be adsorbed on the surface of $$AgI$$ thereby giving a negative charged sol.
$$AgI + \mathop {{I^ - }}\limits_{\left( {{\text{From}}\,\,KI} \right)} \to \mathop {AgI:{I^ - }}\limits_{{\text{Negative}}\,\,{\text{sol}}} $$