D and F Block Elements MCQ Questions & Answers in Inorganic Chemistry | Chemistry

Learn D and F Block Elements MCQ questions & answers in Inorganic Chemistry are available for students perparing for IIT-JEE, NEET, Engineering and Medical Enternace exam.

181. $$F{e^{3 + }}$$  compounds are more stable than $$F{e^{2 + }}$$  compounds because

A $$F{e^{3 + }}$$  has smaller size than $$F{e^{2 + }}$$
B $$F{e^{3 + }}$$  has $$3{d^5}$$ configuration ( half - filled )
C $$F{e^{3 + }}$$  has higher oxidation state
D $$F{e^{3 + }}$$  is paramagnetic in nature
Answer :   $$F{e^{3 + }}$$  has $$3{d^5}$$ configuration ( half - filled )

182. Four successive members of the first row transition elements are listed below with atomic numbers. Which one of them is expected to have the highest $$E_{{M^{3 + }}/{M^{2 + }}}^0$$  value?

A $$Cr\left( {Z = 24} \right)$$
B $$Mn\left( {Z = 25} \right)$$
C $$Fe\left( {Z = 26} \right)$$
D $$Co\left( {Z = 27} \right)$$
Answer :   $$Co\left( {Z = 27} \right)$$

183. Zinc-copper couple that can be used as a reducing agent is obtained by :

A mixing zinc dust and copper gauze
B zinc coated with copper
C copper coated with zinc
D zinc and copper wires welded together
Answer :   mixing zinc dust and copper gauze

184. Which of the following statements is wrong?

A $$T{i^{4 + }}$$ and $$A{g^ + }$$ are repelled by magnetic field.
B $$M{n^{2 + }}$$ shows maximum magnetic character among the first transition series.
C $$F{e^{2 + }}$$ is more stable than $$M{n^{2 + }}$$ towards oxidation to +3 state.
D $$Mn$$  in $$MnO_4^ - $$  ion involves $$s{p^3}$$  hybridisation.
Answer :   $$F{e^{2 + }}$$ is more stable than $$M{n^{2 + }}$$ towards oxidation to +3 state.

185. Highest oxidation state of manganese in fluorides is $$ + 4\left( {Mn{F_4}} \right)$$   but highest oxidation state in oxides is $$ + 7\left( {M{n_2}{O_7}} \right)$$   because

A fluorine is more electronegative than oxygen
B fluorine does not possess $$d$$ - orbitals
C fluorine stabilises lower oxidation state
D in covalent compounds, fluorine can form single bond only while oxygen forms double bond
Answer :   in covalent compounds, fluorine can form single bond only while oxygen forms double bond

186. Which one of the following is a '$$d$$ - block element'?

A $$Gd$$
B $$Hs$$
C $$Es$$
D $$Cs$$
Answer :   $$Hs$$

187. The second and third row elements of transition metals resemble each other much more than they resemble the first row because of

A lanthanoid contraction which results in almost same radii of second and third row metals
B diagonal relationship between second and third row elements
C similar ionisation enthalpy of second and third row elements
D similar oxidation states of second and third row metals
Answer :   lanthanoid contraction which results in almost same radii of second and third row metals

188. Lanthanoid contraction is due to increase in

A atomic number
B effective nuclear charge
C atomic radius
D valence electrons
Answer :   effective nuclear charge

189. In which of the following compounds manganese has oxidation number equal to that of iodine in $$KI{O_4}?$$

A Potassium manganate
B Potassium permanganate
C Dimanganese decacarbonyl
D Manganese chloride
Answer :   Potassium permanganate

190. Bell-metal is an alloy of

A $$Cu + Pb$$
B $$Cu + Sn$$
C $$Cu + Zn$$
D $$Cu + Ni$$
Answer :   $$Cu + Sn$$