S - Block Elements MCQ Questions & Answers in Inorganic Chemistry | Chemistry
Learn S - Block Elements MCQ questions & answers in Inorganic Chemistry are available for students perparing for IIT-JEE, NEET, Engineering and Medical Enternace exam.
11.
Which is not obtained when metal carbides react with $${H_2}O?$$
12.
Which of the following has lowest thermal stability?
A
$$L{i_2}C{O_3}$$
B
$$N{a_2}C{O_3}$$
C
$${K_2}C{O_3}$$
D
$$R{b_2}C{O_3}$$
Answer :
$$L{i_2}C{O_3}$$
$$L{i_2}C{O_3}$$ is least stable and decomposes on heating unlike other alkali metal carbonates.
$$L{i_2}C{O_3} \to L{i_2}O + C{O_2}$$
13.
Identify $$X, Y$$ and $$Z.$$
$$X$$
$$Y$$
$$Z$$
(a)
$$Ca{\left( {HC{O_3}} \right)_2}$$
$$CaC{O_3}$$
$$Ca{\left( {OH} \right)_2}$$
(b)
$$CaC{O_3}$$
$$Ca{\left( {OH} \right)_2}$$
$$Ca{\left( {HC{O_3}} \right)_2}$$
(c)
$$CaC{O_3}$$
$$CaO$$
$$Ca{\left( {OH} \right)_2}$$
(d)
$$CaC{O_3}$$
$$CaO$$
$$Ca{\left( {HC{O_3}} \right)_2}$$
A
(a)
B
(b)
C
(c)
D
(d)
Answer :
(b)
14.
Both lithium and magnesium display several similar properties due to the diagonal relationship; however, the one which is incorrect is :
A
Both form basic carbonates
B
Both form soluble bicarbonates
C
Both form nitrides
D
Nitrates of both $$Li$$ and $$Mg$$ yield $$N{O_2}$$ and $${O_2}$$ on heating
Answer :
Both form basic carbonates
$$Mg$$ an form basic carbonate like
$$3MgC{O_3}.Mg{\left( {OH} \right)_2}.3{H_2}O$$
While $$Li$$ can form only carbonate $$\left( {L{i_2}C{O_3}} \right),$$ not basic carbonate.
15.
Which of the following statements is not correct regarding preparation of $$NaOH?$$
A
$$NaOH$$ is prepared by electrolysis of sodium chloride in Castner - Kellner cell.
B
Sodium metal discharged at cathode combines with mercury to form sodium amalgam.
C
Chlorine is evolved at anode.
D
Amalgam is heated to separate $$Na$$ and $$Hg.$$
Answer :
Amalgam is heated to separate $$Na$$ and $$Hg.$$
Amalgam is treated with water to give sodium hydroxide and hydrogen gas.
$$2Na\,{\text{ - amalgam}} + 2{H_2}O \to $$ $$2NaOH + 2Hg + {H_2} \uparrow $$
16.
Which of the following metal ions play an important role in muscle contraction ?
A
$${K^ + }$$
B
$$N{a^ + }$$
C
$$M{g^{2 + }}$$
D
$$C{a^{2 + }}$$
Answer :
$$C{a^{2 + }}$$
Calcium $$ion\left( {C{a^{2 + }}} \right)$$ play an important role in muscle contraction
17.
A compound $$(A)$$ is used in preparation of washing soda to recover ammonia in Solvay's process. When $$C{O_2}$$ is bubbled through an aqueous solution of $$(A),$$ the solution turns milky. It is used in white washing due to disinfectant nature. What is the chemical formula of $$A?$$
The smaller the size of the ion, the greater is the degree of hydration, thus degree of hydration is highest for $$L{i^ + }$$ and lowest for $$C{s^ + }.$$ Thus $$L{i^ + }$$ holds more water molecules in its hydration sphere and becomes largest in size among alkali metals and $$C{s^ + }\,ion$$ hold least number of water molecules.
Hence, ionic mobility is highest for $$C{s^ + }$$ ( due to its
smallest size in aqueous solution ) and lowest for $$L{i^ + }.$$ Here the lowest is for $$N{a^ + }.$$ Thus, the order of ionic mobility in aqueous solution is $$C{s^ + } > R{b^ + } > {K^ + } > N{a^ + }$$
19.
Alkali metals are not found in free state due to their highly reactive nature. This is due to
A
their large size and low ionisation enthalpy
B
their large size and high ionisation enthalpy
C
their low ionisation enthalpy and high electron gain enthalpy
D
their tendency to impart colour to the flame
Answer :
their large size and low ionisation enthalpy
Due to large size and low ionisation enthalpy, alkali metal loose there outermost valence electron to give $${M^ + }$$ ions. Hence, they are never found in free state.
20.
A metal $$M$$ readily forms its sulphate $$MS{O_4}$$ which is water soluble. It forms its oxide $$MO$$ which becomes inert on heating. It forms its insoluble hydroxide $$M{\left( {OH} \right)_2}$$ which is soluble in $$NaOH$$ solution. What would be $$M?$$
A
$$Be$$
B
$$Ba$$
C
$$Ca$$
D
$$Mg$$
Answer :
$$Be$$
No explanation is given for this question. Let's discuss the answer together.