Hydrocarbons (Alkane, Alkene and Alkyne) MCQ Questions & Answers in Organic Chemistry | Chemistry
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191.
2-Bromopentane is treated with alcoholic $$KOH$$ solution. What will be the major product formed in this reaction and what is the type of elimination called?
192.
Which of the following names is not correctly matched with the compound?
A
B
C
D
Answer :
The correct name of the compound is 4-chlorotoluene.
193. $$X$$ is :
A
B
C
D
Answer :
194.
Which of the following groups is $$o{\text{ - }}p$$ directing but deactivates benzene ring for electrophilic substitution?
A
$$ - C{H_3}$$
B
$$ - N{H_2}$$
C
$$ - Cl$$
D
$$ - N{O_2}$$
Answer :
$$ - Cl$$
Halogens are electron withdrawing groups due to electronegative nature hence they deactivate benzene ring for electrophilic substitution but are $$o, p$$ - directing.
195.
Of the five isomeric hexanes, the isomer which can give two
monochlorinated compounds is
A
2 - methylpentane
B
2, 2 - dimethylbutane
C
2, 3 - dimethylbutane
D
n - hexane
Answer :
2, 3 - dimethylbutane
Since it contains only two
types of H-atoms hence it will give only two mono
chlorinated compounds viz.
and
196.
Which of the following mentioned is a type of hydrocarbon?
A
Saturated hydrocarbon
B
Unsaturated hydrocarbon
C
Aromatic hydrocarbon
D
All of the above
Answer :
All of the above
Depending upon the types of carbon-carbon bonds present, hydrocarbons can be classified into three main categories -
(i) Saturated hydrocarbons contain $$C - C$$ single bonds.
(ii) Unsaturated hydrocarbons contain $$C = C$$ or $$C \equiv C$$ bonds.
(iii) Aromatic hydrocarbons are special type of cyclic compounds.
197.
Consider the following sequence of reactions \[C{{H}_{3}}CH=C{{H}_{2}}\xrightarrow[700K]{C{{l}_{2}}}A\] \[\xrightarrow[420K,12atm]{N{{a}_{2}}C{{O}_{3}}}B\xrightarrow[\left( \text{ii} \right)NaOH]{\left( \text{i} \right)HOCl}C\]
Compound $$'C'$$ is
A
B
C
D
Answer :
198.
Which one of the following conformations of cyclohexane is chiral ?
A
Boat
B
Twist boat
C
Rigid
D
Chair
Answer :
Twist boat
Chiral conformation will not have plane of symmetry. Since twist boat does not have plane of symmetry it is chiral.
199.
The compound formed when alcoholic solution of ethylene dibromide is heated with granulated zinc is
A
nucleophilic and electrophilic substitution respectively
B
electrophilic and nucleophilic substitution respectively
C
electrophilic substitution in both the reactions
D
nucleophilic substitution in both the reactions
Answer :
electrophilic substitution in both the reactions
Nitration is carried out by the help of electrophile $$NO_2^ + .$$
$$HN{O_3} + 2{H_2}S{O_4} \to $$ $$NO_2^ + + 2HSO_4^ - + {H_3}{O^ + }$$
Halogenation is carried out by the help of electrophile $$C{l^ + }\left( {{X^ + }} \right).$$
$$C{l_2} + FeC{l_3} \to C{l^ + } + FeCl_4^ - $$
Hence, both reactions are electrophilic substitution reactions.